FORMATION OF CATIONIC MOLYBDENUM ETA-2-VINYL COMPLEXES - STRUCTURAL EVIDENCE FOR THE COUPLING OF ETA-2-VINYL AND ALKYNE LIGANDS

被引：31

作者：

CONOLE, GC ^{[1
]}

GREEN, M ^{[1
]}

MCPARTLIN, M ^{[1
]}

REEVE, C ^{[1
]}

WOOLHOUSE, CM ^{[1
]}

机构：

[1] UNIV LONDON KINGS COLL,DEPT CHEM,LONDON WC2R 2LS,ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1988年 / 19期

关键词：

D O I：

10.1039/c39880001310

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

引用

页码：1310 / 1313

页数：4

共 13 条

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[5] ETA-2-VINYL AND ETA-2-KETENYL LIGANDS AS ANALOGS OF 4-ELECTRON ALKYNE LIGANDS
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[6] REVERSIBLE MIGRATION OF A COORDINATED MERCAPTO LIGAND ON TO A METAL-BOUND ALKYNE TO GIVE ETA-2-VINYL COMPLEXES - THE CRYSTAL AND MOLECULAR-STRUCTURE OF [WC(CF3).C(CF3)SPRI(CF3C=CCF3)(ETA-5-C5H5)]
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[7] THE MECHANISTIC ROLE OF ETA-2-VINYL COMPLEXES IN METAL-PROMOTED ALKYNE OLIGOMERIZATIONS - THE CRYSTAL AND MOLECULAR-STRUCTURES OF [W(ETA-5-C(CF3)=C(CF3)C(CO2ME)=C(CO2ME)C(CF3)=C(CF3)SPRI)(ETA-5-C5H5)], [WF(ETA-5-C(=CF2)C(CF3)=C(CO2ME)C(CO2ME)C(CF3)C(CF3)SPRI)(ETA-5-C5H5)], AND [W(ETA-4-C(CF3)C(CF3)=C(ME)C(ME)SPRI)(ETA-2-CF3C=CCF3)(ETA-5-C5H5)])
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[8] REACTION OF CATIONIC CYCLOBUTADIENERUTHENIUM COMPLEXES WITH HYDRIDE ANION DONORS - EVIDENCE FOR THE FORMATION OF ETA-4 (5E) BUTADIENYL SPECIES AND FRAGMENTATION OF THE CYCLOBUTADIENE RING - CRYSTAL-STRUCTURES OF [RU=C(PH)-ETA-3-(C(PH).CH(PH).CH(PH))-(ETA-C5H5)] AND [RU2(ETA-CO)(ETA-(Z)-C(PH)=CH(PH))(CO)2(ETA-4-C4PH4)(ETA-C5H5)]ON
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[9] DAVIDSON JL, 1974, J CHEM SOC CHEM COMM, P706
[10] ISOMERISM AND FLUXIONAL BEHAVIOR IN ETA-2-VINYL COMPLEXES RESULTING IN INVERSION OF CONFIGURATION AT AN ASYMMETRIC CARBON-ATOM - THE CRYSTAL AND MOLECULAR-STRUCTURES OF 2 ISOMERIC FORMS OF [MOCL[ETA-2-C(CF3)C(CF3)(PET3)](CF3C=CCF3)(ETA-5-C5H5)]
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