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STRUCTURE CHANGES AND THE SPIN PHASE-TRANSITION MECHANISM OF A SPIN CROSSOVER COMPLEX, [FE(2-PIC)3]CL2.ETOH
被引:87
作者
:
MIKAMI, M
论文数:
0
引用数:
0
h-index:
0
机构:
Institute for Solid State Physics, University of Tokyo, Minato-ku, Tokyo, Roppongi
MIKAMI, M
论文数:
引用数:
h-index:
机构:
KONNO, M
论文数:
引用数:
h-index:
机构:
SAITO, Y
机构
:
[1]
Institute for Solid State Physics, University of Tokyo, Minato-ku, Tokyo, Roppongi
来源
:
CHEMICAL PHYSICS LETTERS
|
1979年
/ 63卷
/ 03期
关键词
:
D O I
:
10.1016/0009-2614(79)80715-0
中图分类号
:
O64 [物理化学(理论化学)、化学物理学];
学科分类号
:
070304 ;
081704 ;
摘要
:
The crystal structure of the spin crossover complex [Fe(2-pic)3]Cl2·EtOH in its high spin state (298, 150 K) and low spin state (90 K) has been determined. The crystals are monoclinic, P21/c with Z=4 in the two spin states. Pronounced changes in the FeN bond distance (2.195 A for high spin, 2.013 A for low spin on average) and orientational disorder of the ethanol molecule were observed. The complexes and ethanols are both hydrogen bounded to Cl- ions. © 1979.
引用
收藏
页码:566 / 569
页数:4
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[J].
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Univ Copenhagen, HC Orsted Inst, Chem Lab 4, DK-2100 Copenhagen, Denmark
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[J].
CHEMICAL PHYSICS LETTERS,
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SPIN EQUILIBRIUM IN TRIS(2-AMINOMETHYLPYRIDINE)IRON(2) HALIDES
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[J].
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EFFECTIVE IONIC RADII IN OXIDES AND FLUORIDES
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ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL CRYSTALLOGRAPHY AND CRYSTAL CHEMISTRY,
1969,
B 25
: 925
-
&
[7]
MOSSBAUER-EFFECT STUDY ON LOW-SPIN A-1(1) REVERSIBLE HIGH-SPIN T-5(2) TRANSITION IN TRIS(2-PICOLYLAMINE) IRON CHLORIDE .1. DILUTION EFFECT IN [FEXZN1-X(2-PIC)3]CL2.C2H5OH
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UNIV MAINZ, INST ANORG & ANAL CHEM, D-6500 MAINZ, GERMANY
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: 199
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209
[8]
MOSSBAUER-EFFECT STUDY ON LOW-SPIN 1A1 REVERSIBLE HIGH-SPIN 5T2 TRANSITION IN [FE(2-PIC)3]CL2 .2. INFLUENCE OF NON-COORDINATING SOLVENT MOLECULE IN [FE(2-PIC)3]CL2.X,X=C2H5OH,CH3OH,H2O AND 2H2O
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UNIV MAINZ,INST ANORGAN & ANALYT CHEM,D-6500 MAINZ,FED REP GER
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PHONON COUPLED COOPERATIVE LOW-SPIN A-1 (1) REVERSIBLE HIGH-SPIN T-5(2) TRANSITION IN [FE(PHEN)2(NCS)2] AND [FE(PHEN)2(NCSE)2] CRYSTALS
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机构:
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SEKI, S
[J].
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共 9 条
[1]
HIGH-SPIN AND LOW-SPIN ALPHA-PICOLYLAMINE IRON(II) COMPLEXES - EFFECT OF LIGAND REVERSAL ON SPIN STATE
GREENAWAY, AM
论文数:
0
引用数:
0
h-index:
0
机构:
UNIV VIRGINIA,DEPT CHEM,CHARLOTTESVILLE,VA 22901
UNIV VIRGINIA,DEPT CHEM,CHARLOTTESVILLE,VA 22901
GREENAWAY, AM
SINN, E
论文数:
0
引用数:
0
h-index:
0
机构:
UNIV VIRGINIA,DEPT CHEM,CHARLOTTESVILLE,VA 22901
UNIV VIRGINIA,DEPT CHEM,CHARLOTTESVILLE,VA 22901
SINN, E
[J].
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,
1978,
100
(26)
: 8080
-
8085
[2]
GUTLICH P, COMMUNICATION
[3]
The Fe-N bond lengths, the "ionic radii" of iron (II), and the crystal field parameters (10Dq) in a high-spin and low-spin [Fe-II-N-6] complex
Koenig, Edgar
论文数:
0
引用数:
0
h-index:
0
机构:
Univ Erlangen Nurnberg, Inst Phys Chem 2, D-8520 Erlangen, Germany
Univ Erlangen Nurnberg, Inst Phys Chem 2, D-8520 Erlangen, Germany
Koenig, Edgar
Watson, K. J.
论文数:
0
引用数:
0
h-index:
0
机构:
Univ Copenhagen, HC Orsted Inst, Chem Lab 4, DK-2100 Copenhagen, Denmark
Univ Erlangen Nurnberg, Inst Phys Chem 2, D-8520 Erlangen, Germany
Watson, K. J.
[J].
CHEMICAL PHYSICS LETTERS,
1970,
6
(05)
: 457
-
459
[4]
MIKAMI M, UNPUBLISHED
[5]
SPIN EQUILIBRIUM IN TRIS(2-AMINOMETHYLPYRIDINE)IRON(2) HALIDES
RENOVITCH, GA
论文数:
0
引用数:
0
h-index:
0
RENOVITCH, GA
BAKER, WA
论文数:
0
引用数:
0
h-index:
0
BAKER, WA
[J].
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,
1967,
89
(24)
: 6377
-
+
[6]
EFFECTIVE IONIC RADII IN OXIDES AND FLUORIDES
SHANNON, RD
论文数:
0
引用数:
0
h-index:
0
SHANNON, RD
PREWITT, CT
论文数:
0
引用数:
0
h-index:
0
PREWITT, CT
[J].
ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL CRYSTALLOGRAPHY AND CRYSTAL CHEMISTRY,
1969,
B 25
: 925
-
&
[7]
MOSSBAUER-EFFECT STUDY ON LOW-SPIN A-1(1) REVERSIBLE HIGH-SPIN T-5(2) TRANSITION IN TRIS(2-PICOLYLAMINE) IRON CHLORIDE .1. DILUTION EFFECT IN [FEXZN1-X(2-PIC)3]CL2.C2H5OH
SORAI, M
论文数:
0
引用数:
0
h-index:
0
机构:
UNIV MAINZ, INST ANORG & ANAL CHEM, D-6500 MAINZ, GERMANY
UNIV MAINZ, INST ANORG & ANAL CHEM, D-6500 MAINZ, GERMANY
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ENSLING, J
论文数:
0
引用数:
0
h-index:
0
机构:
UNIV MAINZ, INST ANORG & ANAL CHEM, D-6500 MAINZ, GERMANY
UNIV MAINZ, INST ANORG & ANAL CHEM, D-6500 MAINZ, GERMANY
ENSLING, J
GUTLICH, P
论文数:
0
引用数:
0
h-index:
0
机构:
UNIV MAINZ, INST ANORG & ANAL CHEM, D-6500 MAINZ, GERMANY
UNIV MAINZ, INST ANORG & ANAL CHEM, D-6500 MAINZ, GERMANY
GUTLICH, P
[J].
CHEMICAL PHYSICS,
1976,
18
(1-2)
: 199
-
209
[8]
MOSSBAUER-EFFECT STUDY ON LOW-SPIN 1A1 REVERSIBLE HIGH-SPIN 5T2 TRANSITION IN [FE(2-PIC)3]CL2 .2. INFLUENCE OF NON-COORDINATING SOLVENT MOLECULE IN [FE(2-PIC)3]CL2.X,X=C2H5OH,CH3OH,H2O AND 2H2O
SORAI, M
论文数:
0
引用数:
0
h-index:
0
机构:
UNIV MAINZ,INST ANORGAN & ANALYT CHEM,D-6500 MAINZ,FED REP GER
UNIV MAINZ,INST ANORGAN & ANALYT CHEM,D-6500 MAINZ,FED REP GER
SORAI, M
ENSLING, J
论文数:
0
引用数:
0
h-index:
0
机构:
UNIV MAINZ,INST ANORGAN & ANALYT CHEM,D-6500 MAINZ,FED REP GER
UNIV MAINZ,INST ANORGAN & ANALYT CHEM,D-6500 MAINZ,FED REP GER
ENSLING, J
HASSELBACH, KM
论文数:
0
引用数:
0
h-index:
0
机构:
UNIV MAINZ,INST ANORGAN & ANALYT CHEM,D-6500 MAINZ,FED REP GER
UNIV MAINZ,INST ANORGAN & ANALYT CHEM,D-6500 MAINZ,FED REP GER
HASSELBACH, KM
GUTLICH, P
论文数:
0
引用数:
0
h-index:
0
机构:
UNIV MAINZ,INST ANORGAN & ANALYT CHEM,D-6500 MAINZ,FED REP GER
UNIV MAINZ,INST ANORGAN & ANALYT CHEM,D-6500 MAINZ,FED REP GER
GUTLICH, P
[J].
CHEMICAL PHYSICS,
1977,
20
(02)
: 197
-
208
[9]
PHONON COUPLED COOPERATIVE LOW-SPIN A-1 (1) REVERSIBLE HIGH-SPIN T-5(2) TRANSITION IN [FE(PHEN)2(NCS)2] AND [FE(PHEN)2(NCSE)2] CRYSTALS
SORAI, M
论文数:
0
引用数:
0
h-index:
0
机构:
OSAKA UNIV,FAC SCI,DEPT CHEM,TOYONAKA 560,OSAKA,JAPAN
OSAKA UNIV,FAC SCI,DEPT CHEM,TOYONAKA 560,OSAKA,JAPAN
SORAI, M
SEKI, S
论文数:
0
引用数:
0
h-index:
0
机构:
OSAKA UNIV,FAC SCI,DEPT CHEM,TOYONAKA 560,OSAKA,JAPAN
OSAKA UNIV,FAC SCI,DEPT CHEM,TOYONAKA 560,OSAKA,JAPAN
SEKI, S
[J].
JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS,
1974,
35
(04)
: 555
-
570
←
1
→