DOES THE RHODIUM-CATALYZED ADDITION OF PERHALOALKANES TO ALKENES (IE THE KHARASCH REACTION) PROCEED VIA AN OXIDATIVE-ADDITION MECHANISM - THE CRYSTAL-STRUCTURE OF RHBR(CCL3)CL(CO)(PME3)2

被引：16

作者：

CABLE, CJ

ADAMS, H

BAILEY, NA

CROSBY, J

WHITE, C

机构：

[1] UNIV SHEFFIELD,DEPT CHEM,SHEFFIELD S3 7HF,S YORKSHIRE,ENGLAND

[2] ICI PLC,FINE CHEM MFG ORG,MANCHESTER M9 3DA,LANCS,ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1991年 / 03期

关键词：

D O I：

10.1039/c39910000165

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Evidence is presented to show that rhodium(I)-catalysed Kharasch reactions may proceed via oxidative-addition of the perhalocarbon to the Rh followed by stepwise transfer to a coordinated alkene.

引用

页码：165 / 166

页数：2

共 18 条

[1] CHLORINE-ACTIVATION BY REDOX-TRANSFER .3. ABNORMAL ADDITION OF CHLOROFORM TO OLEFINS
ASSCHER, M
VOFSI, D
[J]. JOURNAL OF THE CHEMICAL SOCIETY, 1963, (AUG): : 3921 - &
[2] CHLORINE ACTIVATION BY REDOX TRANSFER .2. ADDITION OF CARBON TETRACHLORIDE TO OLEFINS
ASSCHER, M
VOFSI, D
[J]. JOURNAL OF THE CHEMICAL SOCIETY, 1963, (MAR): : 1887 - &
[3] BABUSHKINA TA, 1968, ZH STRUKT KHIM, V9, P207
[4] TRANSITION-METAL TRIHALOMETHYL COMPLEXES AS CLUSTER-BUILDING REAGENTS - PREPARATION AND X-RAY CRYSTAL-STRUCTURE OF [PPN][MNCO2(CO)9(MU-3-CCO)]
CRESPI, AM
WENT, MJ
SUNSHINE, SS
SHRIVER, DF
[J]. ORGANOMETALLICS, 1988, 7 (01) : 214 - 218
[5] THE ADDITION OF HALOGENOCARBONS TO ALKENES IN THE PRESENCE OF [FE2(CO)4(ETA-C5H5)2] AND RELATED COMPLEXES
DAVIS, R
DURRANT, JLA
KHAZAL, NMS
BITTERWOLF, TE
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1990, 386 (02) : 229 - 239
[6] THE REACTION OF TETRACHLOROMETHANE WITH OCT-1-ENE IN THE PRESENCE OF [MO2(CO)6(ETA-5-C5H5)2] AND OTHER TRANSITION-METAL COMPLEXES
DAVIS, R
GROVES, IF
[J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1982, (11): : 2281 - 2287
[7] HALOALKYL COMPLEXES OF THE TRANSITION-METALS .4. THE FORMATION OF A CATIONIC YLIDE COMPLEX OF PLATINUM(II) FROM A CHLOROMETHYLPLATINUM(II) COMPLEX AND THE CRYSTAL-STRUCTURES OF CIS-[P+(CH2PPH3)CL(PPH3I, CCIS-[P+(CH2PPH3)I(PPH3)2]I
ENGELTER, C
MOSS, JR
NASSIMBENI, LR
NIVEN, ML
REID, G
SPIERS, JC
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1986, 315 (02) : 255 - 268
[8] FREIDLIN.RK, 1974, SYNTHESIS-STUTTGART, P477
[9] NAPHTHALENECHROMIUM TRICARBONYL-CATALYZED ADDITION OF CARBON-TETRACHLORIDE TO OLEFINS AT AMBIENT-TEMPERATURES
GANDOLFI, O
CAIS, M
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1977, 125 (01) : 141 - 154
[10] RUTHENIUM(II)-CATALYZED AND RHENIUM(III)-CATALYZED ADDITION OF TETRAHALOGENOMETHANES TO ALKENES AND 1, OMEGA-DIENES - STEREOSELECTIVE FORMATION OF CIS-1,2-DISUBSTITUTED CYCLOPENTANES FROM 1,6-DIENES
GRIGG, R
DEVLIN, J
RAMASUBBU, A
SCOTT, RM
STEVENSON, P
[J]. JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1987, (07): : 1515 - 1520

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