THE NATURE OF GAS-PHASE COMPLEXES R3P-H-X (R = H, CH3 X = CL, BR, I)

被引：8

作者：

MULLER, B ^{[1
]}

REINHOLD, J ^{[1
]}

机构：

[1] UNIV LEIPZIG,FACHBEREICH CHEM,TALSTR 35,O-7010 LEIPZIG,GERMANY

来源：

CHEMICAL PHYSICS LETTERS | 1992年 / 196卷 / 3-4期

关键词：

D O I：

10.1016/0009-2614(92)85983-H

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

There is no evidence for the existence of anion-pair complex R3PH+-X- in the gas phase. The corresponding minimum on the SCF potential surface in the case of R = CH3 disappears after inclusion of correlation energy contributions.

引用

页码：363 / 367

页数：5

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