THE NATURE OF GAS-PHASE COMPLEXES R3P-H-X (R = H, CH3 X = CL, BR, I)

被引:8
作者
MULLER, B [1 ]
REINHOLD, J [1 ]
机构
[1] UNIV LEIPZIG,FACHBEREICH CHEM,TALSTR 35,O-7010 LEIPZIG,GERMANY
关键词
D O I
10.1016/0009-2614(92)85983-H
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
There is no evidence for the existence of anion-pair complex R3PH+-X- in the gas phase. The corresponding minimum on the SCF potential surface in the case of R = CH3 disappears after inclusion of correlation energy contributions.
引用
收藏
页码:363 / 367
页数:5
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