BIS(PHTHALOCYANINATO)ERBIUM (ALPHA-1 PHASE)

被引：21

作者：

OSTENDORP, G

WERNER, JP

HOMBORG, H

机构：

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1995年 / 51卷 / pt 6期

关键词：

D O I：

10.1107/S0108270195000126

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

In the title compound, alpha 1-bis(phthalocyaninato)erbium {alpha 1-[Er(Pc)(2)], where Pc = C32H16N82-/-}, Er-III is eightfold coordinated by the isoindole N atoms (N-iso) of the two staggered (41.4 degrees) saucer-shaped Pc ligands. The Er-N-iso distance is 2.41 (1) Angstrom; the height of the slightly distorted ErN8 square antiprism is 2.74 Angstrom. The [Er(Pc)(2)] molecules are packed in columns parallel to the tetragonal c axis. In this new tetragonal alpha 1 phase, the disposition of the metal ion is ordered and the Pc rings are structurally equivalent.

引用

页码：1125 / 1128

页数：4

共 23 条

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