HYDROGEN TRANSFER-REACTIONS CATALYZED BY CATIONIC RHODIUM(I) COMPLEXES

被引：26

作者：

SPOGLIARICH, R

ZASSINOVICH, G

MESTRONI, G

GRAZIANI, M

机构：

[1] Istituto di Chimica, Università di Trieste, Trieste

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1979年 / 179卷 / 03期

关键词：

D O I：

10.1016/S0022-328X(00)91754-6

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Hydrogen transfer from isopropanol to various ketones such as cyclohexanone, 4-t-butylcyclohexanone and acetophenone are catalyzed by cationic rhodium(I) complexes of the type [Rh(Diene)L2]+ (Diene = 1,5-cyclooctadiene (COD) or norbornadiene (NBD); L2 or L = mono- or bi-dentate phosphine ligands). The results indicate higher activities for complexes containing chelating ligands. © 1979.

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页码：C45 / C47

页数：3

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