TRISPYRAZOLYLBORATE DEGRADATION IN RHODIUM COMPLEXES - CRYSTAL-STRUCTURE OF [RH(3-BU(T)-C3N2H2)(NBD)(3-BU(T)-C3N2H3)]

被引：10

作者：

CANO, M

CAMPO, JA

HERAS, JV

PINILLA, E

RIVAS, C

MONGE, A

机构：

[1] CSIC,INST CIENCIA MAT,SEDE D,E-28006 MADRID,SPAIN

[2] UNIV COMPLUTENSE MADRID,FAC CIENCIAS QUIM,LAB DIFRAC RAYOS X,E-28040 MADRID,SPAIN

来源：

POLYHEDRON | 1994年 / 13卷 / 15-16期

关键词：

D O I：

10.1016/S0277-5387(00)88164-4

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of [Rh(mu-Cl)(NBD)](2) (NBD = 2,5-norbornadiene) and [TpBu(t)](-)(TpBu(t) = hydrotris(3-tert-butylpyrazol-1-yl)borate, HB[3-Bu(t)pz](3)) yields [Rh(3-Bu(t)pz) (NBD)(3-Bu(t)pzH)] (pz = C3N2H2) instead of the expected complex [Rh(TpBu(t))(NBD)]. The crystal structure of the title compound shows the presence of an asymmetric H bond between the two pyrazole rings. The formation of the pyrazole/pyrazolate complex implies a degradation reaction of the ligand.

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页码：2463 / 2465

页数：3

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