A COMPARATIVE-STUDY OF OXIDES FOR M-CRESOL ALKYLATION

被引：20

作者：

DURGAKUMARI, V ^{[1
]}

NARAYANAN, S ^{[1
]}

机构：

[1] INDIAN INST CHEM TECHNOL,CATALYSIS SECT,HYDERABAD 500007,INDIA

来源：

JOURNAL OF MOLECULAR CATALYSIS | 1991年 / 65卷 / 03期

关键词：

D O I：

10.1016/0304-5102(91)85073-B

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Simple and mixed oxides such as V2O5, MgO, V2O5/Cr2O3, Fe2O3/ZnO, MgO/Al2O3 and MgO/TiO2 were screened for gas phase alkylation of m-cresol. The dependence of activity and selectivity on the acid-base properties of these catalysts is discussed. On acid catalysts this reaction is possible at 673 K and below, whereas on basic catalysts it takes place above 773 K. The effect of modification of the acidity and basicity of the catalysts with the addition of a second oxide on this reaction is also discussed.

引用

页码：385 / 392

页数：8

共 19 条

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