PIGMENTS OF FUNGI .38. SYNTHESIS OF AUSTROCORTICINIC ACID AND (S)-(-)AUSTROCORTICIN - ABSOLUTE STEREOCHEMISTRY OF NATURAL AUSTROCORTICIN

被引：17

作者：

COTTERILL, AS ^{[1
]}

GILL, M ^{[1
]}

GIMENEZ, A ^{[1
]}

MILANOVIC, NM ^{[1
]}

机构：

[1] UNIV MELBOURNE,SCH CHEM,PARKVILLE,VIC 3052,AUSTRALIA

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | 1994年 / 22期

关键词：

D O I：

10.1039/p19940003269

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The absolute configuration of the fungal anthraquinone (+)-austrocorticin 1 is established as (R) by synthesis of its antipode 5 from (S)-(-)-but-3-yn-2-ol via a Diels-Alder reaction involving the highly functionalised, chiral butadiene 6. Similarly, austrocorticinic acid is made available from but-1-yne.

引用

页码：3269 / 3276

页数：8

共 18 条

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