HYDROTHERMAL SYNTHESIS AND CRYSTAL-STRUCTURE OF MN(SEO3)2

被引：23

作者：

GIESTER, G

WILDNER, M

机构：

[1] Institut für Mineralogie, Kristallographie der Universität Wien, A-1010 Wien

来源：

JOURNAL OF SOLID STATE CHEMISTRY | 1991年 / 91卷 / 02期

关键词：

D O I：

10.1016/0022-4596(91)90092-V

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Crystals of Mn(SeO3)2 were prepared by hydrothermal synthesis; the crystal structure was determined by direct and Fourier methods using single crystal X-ray data up to sin θ λ = 0.9 Å-1 [monoclinic, space group P21 n (C52h, No. 14) Z = 2, a = 5.061(1) Å, b = 6.660(1) Å, c = 7.255(1) Å, β = 91.01(1)°; R = 0.021 for 1458 reflections]. Isolated Mn(IV)O6 octahedra (mean MnO: 1.891 Å) are connected via Se(IV)O3 pyramids (mean SeO: 1.716 Å) to a framework structure. © 1991.

引用

页码：370 / 374

页数：5