A NEW NICKEL(II) CYCLAM (CYCLAM = 1,4,8,11-TETRAAZACYCLOTETRADECANE) COMPLEX COVALENTLY ATTACHED TO RU(PHEN)3(2+) (PHEN = 1,10-PHENANTHROLINE) - A NEW CANDIDATE FOR THE CATALYTIC PHOTOREDUCTION OF CARBON-DIOXIDE

被引：153

作者：

KIMURA, E

BU, XH

SHIONOYA, M

WADA, SJ

MARUYAMA, S

机构：

[1] Department of Medicinal Chemistry, School of Medicine, Hiroshima University, Hiroshima 734, Kasumi 1-2-3, Minami-ku

[2] Department of Chemistry, Nankai University

来源：

INORGANIC CHEMISTRY | 1992年 / 31卷 / 22期

关键词：

D O I：

10.1021/ic00048a020

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A bifunctional supramolecular complex Ru(phen)2(phen-cyclam-Ni)(ClO4)4 (6) (phen-cyclam = 1-(1,10-phenanthrolin-5-ylmethyl)-1,4,8,11-tetraazacyclotetradecane) has been newly synthesized, and its spectroscopic, redox properties, and catalytic behavior in the photoreduction Of CO2 have been examined. The new binuclear complex 6 is shown to be an interesting hybrid molecule composed of a Ru(phen)3(2+) (phen = 1,10-phenanthroline) subunit, which acts as a photosensitizer, and a Ni(cyclam)2+ catalytic reduction site.

引用

页码：4542 / 4546

页数：5

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