INCORPORATION OF COBALT CARBONYL INTO POLY(CARBOSILANE)S CONTAINING MAIN-CHAIN ACETYLENE AND AROMATIC-GROUPS

被引：6

作者：

CORRIU, RJP ^{[1
]}

DOUGLAS, WE ^{[1
]}

YANG, ZX ^{[1
]}

机构：

[1] UNIV MONTPELLIER 2,CNRS,UMR 44,UNITE MIXTE CNRS RHONE POULENC 2,PL EUGENE BATAILLON,F-34095 MONTPELLIER 5,FRANCE

来源：

POLYMER | 1993年 / 34卷 / 16期

关键词：

POLY(CARBOSILANE)S; ACETYLENE; COBALT;

D O I：

10.1016/0032-3861(93)90489-W

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The polymers -(SiR1R2-C=C-(4,4'-C6H4C6H4)-C=C-)n (where R1R2=Ph2 or Meoct(n)) react with dicobalt octacarbonyl to give the corresponding polymers containing either all or half the acetylenes complexed by Co2(CO)6 groups depending on the reactant proportions. These polymers of different stoichiometry can be distinguished by C-13 and Si-29 n.m.r. spectroscopy.

引用

页码：3535 / 3537

页数：3

共 8 条

[1] SYNTHESIS, CHARACTERIZATION AND OPTICAL-PROPERTIES OF METAL-CONTAINING POLYDIACETYLENES
AGHATABAY, NM
LINDSELL, WE
PRESTON, PN
TOMB, PJ
LLOYD, AD
RANGELROJO, R
SPRUCE, G
WHERRETT, BS
[J]. JOURNAL OF MATERIALS CHEMISTRY, 1992, 2 (12) : 1241 - 1247
[2] (ETHYNYLHYDROSILANE)COBALT CARBONYL-COMPLEXES - REACTIVITY OF THE SILICON HYDROGEN-BOND
CORRIU, RJP
MOREAU, JJE
PRAET, H
[J]. ORGANOMETALLICS, 1990, 9 (07) : 2086 - 2091
[3] COBALT CARBONYL-COMPLEXES OF FUNCTIONAL ETHYNYLSILANES - REACTIVITY AT THE SILICON ATOM
CORRIU, RJP
MOREAU, JJE
PRAET, H
[J]. ORGANOMETALLICS, 1989, 8 (12) : 2779 - 2786
[4] ELECTRICAL-CONDUCTIVITY OF FECL3-DOPED POLY(ALKYNYLSILANE)S
CORRIU, RJP
DOUGLAS, WE
YANG, ZX
GARNIER, F
YASSAR, A
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1991, 417 (03) : C50 - C52
[5] SYNTHESIS OF POLY(ALKYNYLSILANES) HAVING VARIOUS AROMATIC-GROUPS IN THE BACKBONE
CORRIU, RJP
DOUGLAS, WE
YANG, ZX
[J]. JOURNAL OF POLYMER SCIENCE PART C-POLYMER LETTERS, 1990, 28 (13) : 431 - 437
[6] CORRIU RJP, IN PRESS EUR POLYM J
[7] CROSS GH, 1992, JUL SPIE INT S OPT A
[8] SYNTHESIS AND NMR-SPECTROSCOPY OF ORGANOMETALLICALLY-SUBSTITUTED DICOBALTHEXACARBONYL-ALKYNE COMPLEXES
GALOW, P
SEBALD, A
WRACKMEYER, B
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1983, 259 (03) : 253 - 268

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