ZIRCONIUM-MEDIATED RING-OPENING OF CYCLOPROPANES

被引：22

作者：

DIMMOCK, PW ^{[1
]}

WHITBY, RJ ^{[1
]}

机构：

[1] UNIV SOUTHAMPTON,DEPT CHEM,SOUTHAMPTON SO17 1BJ,HANTS,ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1994年 / 20期

关键词：

D O I：

10.1039/c39940002323

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Zirconocene eta(2)-alkene and eta(2)-imine complexes with adjacent cyclopropane rings undergo cyclopropane ring cleavage to afford novel eta(3)-allyl, eta(3)-azaallyl, and eta(1)-enamine complexes.

引用

页码：2323 / 2324

页数：2

共 24 条

[1] CHEMOSELECTIVE FUNCTIONALIZATION OF ZIRCONACYCLOPENTENES
AOYAGI, K
KASAI, K
KONDAKOV, DY
HARA, R
SUZUKI, N
TAKAHASHI, T
[J]. INORGANICA CHIMICA ACTA, 1994, 220 (1-2) : 319 - 326
[2] VINYLCARBENE COMPLEXES OF TITANOCENE
BINGER, P
MULLER, P
BENN, R
MYNOTT, R
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 1989, 28 (05) : 610 - 611
[3] METALLACYCLOBUTENES VIA ETA-2-CYCLOPROPENE COMPLEXES OF TITANOCENE AND ZIRCONOCENE
BINGER, P
MULLER, P
HERRMANN, AT
PHILIPPS, P
GABOR, B
LANGHAUSER, F
KRUGER, C
[J]. CHEMISCHE BERICHTE-RECUEIL, 1991, 124 (10): : 2165 - 2170
[4] DIMETHYLALLENEDIYL AS AN ETA-1,ETA-2-BRIDGING LIGAND IN A DIZIRCONOCENE COMPLEX
BINGER, P
LANGHAUSER, F
GABOR, B
MYNOTT, R
HERRMANN, AT
KRUGER, C
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1992, (06) : 505 - 506
[5] METALLABICYCLO(3.1.0)HEXENES AND THEIR REARRANGEMENT TO VINYLMETALLACYCLOBUTENES (M = TI, ZR)
BINGER, P
MULLER, P
LANGHAUSER, F
SANDMEYER, F
PHILIPPS, P
GABOR, B
MYNOTT, R
[J]. CHEMISCHE BERICHTE-RECUEIL, 1993, 126 (07): : 1541 - 1550
[6] ZIRCONOCENE COMPLEXES OF UNSATURATED ORGANIC-MOLECULES - NEW VEHICLES FOR ORGANIC-SYNTHESIS
BROENE, RD
BUCHWALD, SL
[J]. SCIENCE, 1993, 261 (5129) : 1696 - 1701
[7] ZIRCONOCENE COMPLEXES OF IMINES - GENERAL-SYNTHESIS, STRUCTURE, REACTIVITY, AND INSITU GENERATION TO PREPARE GEOMETRICALLY PURE ALLYLIC AMINES
BUCHWALD, SL
WATSON, BT
WANNAMAKER, MW
DEWAN, JC
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1989, 111 (12) : 4486 - 4494
[8] COLES N, 1992, SYNLETT, P143
[9] COLES N, 1990, SYNLETT, P271
[10] STRUCTURE-REACTIVITY CORRELATIONS FOR THE FORMATION OF ZIRCONOCENE ETA-2-IMINE COMPLEXES FROM AMINES
COLES, N
HARRIS, MCJ
WHITBY, RJ
BLAGG, J
[J]. ORGANOMETALLICS, 1994, 13 (01) : 190 - 199

← 1 2 3 →