SYNTHESIS AND STRUCTURE OF THE DISTORTED OCTAHEDRAL PALLADIUM(II) COMPLEX [PD(TMPP)(2)][BF4](2) [TMPP NUMBER TRIS(2.4,6-TRIMETHOXYPHENYL)PHOSPHINE]

被引：41

作者：

DUNBAR, KR

SUN, JS

机构：

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1994年 / 20期

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D O I：

10.1039/c39940002387

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The brick-red Pd-II complex [Pd(tmpp)(2)][BF4](2) is isolated from the reaction of [Pd(NCCH3)(4)][BF4](2) and tmpp (tris(2,4,6-trimethoxyphenyl)phosphine) (2 equiv.) in acetone at -44 degrees C; the new phosphine compound constitutes a rare example of a distorted octahedral Pd-II compound and exhibits the shortest Pd-L(ax) distances reported to date for six-coordinate Pd-II complexes.

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页码：2387 / 2388

页数：2

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