SOLID-STATE IONICS - HIGH COPPER-ION CONDUCTIVITY OF THE SYSTEM CUCL-CUL-RBCL

被引：122

作者：

TAKAHASHI, T

YAMAMOTO, O

YAMADA, S

HAYASHI, S

机构：

[1] Department of Applied Chemistry, Faculty of Engineering, Nagoya University

来源：

JOURNAL OF THE ELECTROCHEMICAL SOCIETY | 1979年 / 126卷 / 10期

关键词：

copper (I) halide; copper ion conductor; rubidium chloride; solid electrolyte;

D O I：

10.1149/1.2128770

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

A new high copper ion conductivity solid electrolyte Rb4Cu16I7Cl13 has been found in the CuCI-Cul-RbCI system. This compound has a copper ion conductivity of 0.34 (Ω-cm)-1 at 25°C, and activation energies for conduction of 7.0 kJ/mole between 130°C and − 25°C, and 19 kJ/mole between -25°C and -140° C, respectively. Powder x-ray diffraction analysis indicates that the crystal structure of Rb4Cu16I7Cl13 is simple cubic with a = 10.02Å. © 1979, The Electrochemical Society, Inc. All rights reserved.

引用

页码：1654 / 1658

页数：5

共 22 条

[1] ELECTRICAL-CONDUCTIVITY OF KCU4I5 [J].