共 22 条
[21]
Warburg E, 1901, ANN PHYS-BERLIN, V6, P125
[22]
[No title captured]
SOLID-STATE IONICS - HIGH COPPER-ION CONDUCTIVITY OF THE SYSTEM CUCL-CUL-RBCL
被引：122
作者：
TAKAHASHI, T
YAMAMOTO, O
YAMADA, S
HAYASHI, S
机构：
[1] Department of Applied Chemistry, Faculty of Engineering, Nagoya University
关键词：
copper (I) halide;
copper ion conductor;
rubidium chloride;
solid electrolyte;
D O I：
10.1149/1.2128770
中图分类号：
O646 [电化学、电解、磁化学];
学科分类号：
081704 ;
摘要：
A new high copper ion conductivity solid electrolyte Rb4Cu16I7Cl13 has been found in the CuCI-Cul-RbCI system. This compound has a copper ion conductivity of 0.34 (Ω-cm)-1 at 25°C, and activation energies for conduction of 7.0 kJ/mole between 130°C and − 25°C, and 19 kJ/mole between -25°C and -140° C, respectively. Powder x-ray diffraction analysis indicates that the crystal structure of Rb4Cu16I7Cl13 is simple cubic with a = 10.02Å. © 1979, The Electrochemical Society, Inc. All rights reserved.
引用
收藏
页码：1654 / 1658
页数：5
相关论文