STRONG AGGREGATION PROPERTIES OF NOVEL NAPHTHALOCYANINES

被引：49

作者：

TAI, S ^{[1
]}

HAYASHI, N ^{[1
]}

机构：

[1] HITACHI CHEM CO LTD,IBARAKI RES LAB,13-1 4-CHOME,HIGASHI,HITACHI 317,JAPAN

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2 | 1991年 / 08期

关键词：

D O I：

10.1039/p29910001275

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The aggregation properties of naphthalocyanines having different ring substituents have been studied in solution. MNc(Bu(t))4 and MNc(OBu(n))4 showed moderate tendencies for aggregation (M = Cu(II), Ni(II), Pd(II) and V(IV) = O). However, novel naphthalocyanines such as MNc(CO2R)4 induced marked aggregation. Especially, MNc(CO2R)4 complexes (M = Cu, Pd and Ni) were found to exist exclusively in aggregated states without monomers even in highly diluted solutions.

引用

页码：1275 / 1279

页数：5

共 36 条

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