SLIPPAGE - AN ALTERNATIVE METHOD FOR ASSEMBLING [2]ROTAXANES

被引：108

作者：

ASHTON, PR ^{[1
]}

BELOHRADSKY, M ^{[1
]}

PHILP, D ^{[1
]}

STODDART, JF ^{[1
]}

机构：

[1] UNIV BIRMINGHAM, SCH CHEM, BIRMINGHAM B15 2TT, W MIDLANDS, ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1993年 / 16期

关键词：

D O I：

10.1039/c39930001269

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The exploitation of size-complementarity between the macrocyclic component and the stoppers of the dumbbell component of a [2]rotaxane, together with stabilising noncovalent bonding interactions that create a thermodynamic trap, have permitted the development of an alternative method, which can be termed slippage, for the syntheses of [2]rotaxanes in good yields.

引用

页码：1269 / 1274

页数：6

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