[RH([9]ANES3)(CO)(PPH3)]+.PF6-

被引：7

作者：

BLAKE, AJ

HALCROW, MA

SCHRODER, M

机构：

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1993年 / 49卷

关键词：

D O I：

10.1107/S0108270192004943

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Carbonyl)(triphenylphosphine-P)(1,4,7-trithiacyclononane-S,S',S'')rhodium hexafluorophosphate, [Rh(C6H12S3)(C18H15P)(CO)]PF6, M(r) = 718.45, orthorhombic, Pnma, a = 12.4367 (8), b = 12.7190 (6), c = 18.0229 (8) angstrom, V = 2850.9 angstrom3, Z = 4, D(x) = 1.674 Mg m-3, lambda(Mo Kalpha) = 0.71073 angstrom, mu = [GRAPHICS] 0.968 mm-1, F(000) = 1448, T = 298 K, R = 0.0498 for 1401 unique observed reflections. The Rh(I) centre is five-coordinate, with the donor atoms conferring a distorted trigonal bipyramidal environment in which the carbonyl group and two of the three thia donors are equatorial and the remaining thia donor and the phosphine are axial.

引用

页码：85 / 87

页数：3

共 7 条

[1] SYNTHESIS, STRUCTURE AND REACTIVITY OF CATIONIC RHODIUM(I) AND IRIDIUM(I) THIOETHER CROWNS - STRUCTURES OF [M([9]ANES3)(COD)]+ (M = RH, IR, COD = CYCLOOCTA-1,5-DIENE) AND [RH([9]ANES3)(C2H4)2]+ ([9]ANES3 = 1,4,7-TRITHIACYCLONONANE) [J].