[GA4(C(SIME3)3)4] WITH A TETRAHEDRAL GA4 SKELETON

被引：147

作者：

UHL, W ^{[1
]}

HILLER, W ^{[1
]}

LAYH, M ^{[1
]}

SCHWARZ, W ^{[1
]}

机构：

[1] TECH UNIV MUNICH,INST ANORGAN CHEM,W-8000 MUNICH 2,GERMANY

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1992年 / 31卷 / 10期

关键词：

D O I：

10.1002/anie.199213641

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The unusual oxidation state I and M4 tetrahedra in the solid-state characterize tris(trimethylsilyl) methylgallium, the disproportionation product of the reaction of Ga2Br4 . 2dioxane with solvent-free LiC-(SiMe3)3. Although only the monomeric unit is detected by mass spectrometry, tetramers (X-ray structure shown here) are found in the solid state.

引用

页码：1364 / 1366

页数：3