NEW CU-TE CLUSTERS

被引:48
作者
FENSKE, D
STECK, JC
机构
[1] Institut Für Anorganische Chemie, Universität Karlsruhe, D-W-7500, Engesserstrasse
来源
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1993年 / 32卷 / 02期
关键词
D O I
10.1002/anie.199302381
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Frank-Kasper polyhedrons suitable for the description of the structures of intermetallic phases can also be used to describe the structures of the Cu-rich clusters, which are among the compounds formed by the reactions of CuCl with phosphanes and Te(Si-Me3)2. The Cu-poor compound 1 in contrast contains a Cu, butterfly cluster with two mu4-Te(2)-2 ligands (structure shown right).
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页码:238 / 242
页数:5
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