PREPARATION OF ELECTRON-RICH CATIONIC COMPLEXES OF THE TYPE [(ETA-5-C5ME5)RU(BIPYRIDINE)L]+

被引：31

作者：

BALAVOINE, GGA ^{[1
]}

BOYER, T ^{[1
]}

LIVAGE, C ^{[1
]}

机构：

[1] UNIV PARIS 11,CNRS,URA 2,PHYS SOLIDES LAB,F-91405 ORSAY,FRANCE

来源：

ORGANOMETALLICS | 1992年 / 11卷 / 01期

关键词：

D O I：

10.1021/om00037a073

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reaction of Cp*Ru(bpy)Cl (Cp* = C5Me5, bpy = 2,2'-bipyridine) with various monodentate two-electron donor ligands (L) in the presence of NH4PF6 gives [Cp*Ru(bpy)L]+PF6- (L = EtO2C-CH = CH-CO2Et; CH2 = CH-CO2Et; EtO2C-C = C-CO2Et; 1,4-epoxy-1,4-dihydronaphthalene; 2,5-dihydrofuran; CO; PPh3). The molecular structure of the ethyl maleate complex determined by X-ray diffraction studies is described.

引用

页码：456 / 459

页数：4

共 16 条

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