PREPARATION OF ELECTRON-RICH CATIONIC COMPLEXES OF THE TYPE [(ETA-5-C5ME5)RU(BIPYRIDINE)L]+

被引:31
作者
BALAVOINE, GGA [1 ]
BOYER, T [1 ]
LIVAGE, C [1 ]
机构
[1] UNIV PARIS 11,CNRS,URA 2,PHYS SOLIDES LAB,F-91405 ORSAY,FRANCE
关键词
D O I
10.1021/om00037a073
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Reaction of Cp*Ru(bpy)Cl (Cp* = C5Me5, bpy = 2,2'-bipyridine) with various monodentate two-electron donor ligands (L) in the presence of NH4PF6 gives [Cp*Ru(bpy)L]+PF6- (L = EtO2C-CH = CH-CO2Et; CH2 = CH-CO2Et; EtO2C-C = C-CO2Et; 1,4-epoxy-1,4-dihydronaphthalene; 2,5-dihydrofuran; CO; PPh3). The molecular structure of the ethyl maleate complex determined by X-ray diffraction studies is described.
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页码:456 / 459
页数:4
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