PREPARATION OF SOME ORGANO-BIS(DIISOPROPYLAMINO)BORANES AND THEIR APPLICATION TO THE SYNTHESIS OF OXAZABOROLIDINES

被引：21

作者：

CHAVANT, PY ^{[1
]}

VAULTIER, M ^{[1
]}

机构：

[1] UNIV RENNES 1,PHYSICOCHIM STRUCT LAB,1 AV GAL LECLERC,F-35042 RENNES,FRANCE

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1993年 / 455卷 / 1-2期

关键词：

D O I：

10.1016/0022-328X(93)80377-N

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reactivity of ClB(NEt2)2 and CIB(NiPr2)2 towards organomagnesium or organolithium derivatives was studied. CIB(NiPr2)2 proved to be an excellent reagent for the preparation of pure boronic derivatives RB(NiPr2)2, which can be used for an efficient synthesis of oxazaborolidines, including Corey's CBS catalyst.

引用

页码：37 / 46

页数：10

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