DECHLORINATION OF OCTACHLORODIBENZO-P-DIOXIN AND OCTACHLORODIBENZOFURAN ON AN ALUMINA SUPPORT

被引：36

作者：

SCHOONENBOOM, MH

ZOETEMEIJER, HE

OLIE, K

机构：

[1] Department of Environmental and Toxicological Chemistry, University of Amsterdam, 1018 WV Amsterdam

来源：

APPLIED CATALYSIS B-ENVIRONMENTAL | 1995年 / 6卷 / 01期

关键词：

ACIDITY; ALUMINA; DECHLORINATION; DESTRUCTION; OCDD; OCDF; METAL CHLORIDES;

D O I：

10.1016/0926-3373(94)00055-7

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

We have studied the dechlorination/destruction of octachlorodibenzo-p-dioxin and octachlorodibenzofuran on alumina. The acidity of the alumina is an important parameter for the dechlorination of these compounds. Alkaline alumina is a better dechlorination agent than acidic alumina. Metal chlorides are less effective dechlorination catalysts than alumina. The dechlorination of octachlorodibenzo-p-dioxin and octachlorodibenzofuran on alumina proceeds probably via an electrophilic substitution mechanism.

引用

页码：11 / 20

页数：10