(2,4-PENTANEDIONATO)VANADIUM(III) AND 2,4-PENTANEDIONATOVANADIUM(II) COMPLEXES - SYNTHESIS FROM THE OXOVANADIUM REDUCTIVE CHLORINATION AND THEIR STRUCTURAL CHARACTERIZATION

被引：11

作者：

SOLARI, E

DEANGELIS, S

FLORIANI, C

CHIESIVILLA, A

GUASTINI, C

机构：

[1] UNIV LAUSANNE,CHIM SECT,PL CHATEAU 3,CH-1005 LAUSANNE,SWITZERLAND

[2] UNIV PARMA,CNR,CTR STRUTT DIFFRATIOMETR,IST STRUTT CHIM,I-43100 PARMA,ITALY

来源：

INORGANIC CHEMISTRY | 1992年 / 31卷 / 01期

关键词：

D O I：

10.1021/ic00027a028

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

In spite of the recent active investigations on vanadium(III) and vanadium(II) chemistry, 2 there are still rather few starting materials easily accessible for (i) organometallic functionalization, (ii) reduction at the metal center, or (iii) solubility in organic solvents for carrying out reactions on oxygen-rich substrates, 3 except for the well-known VC13(THF)34 and [V2(μ-C13)(THF)6]+, 4 which, however, do not contain any ancillary ligands to be usable for the purposes outlined above. In this context we report the synthesis of some vanadium(III) and vanadium(II) acetylacetonate complexes. © 1992, American Chemical Society. All rights reserved.

引用

收藏

页码：141 / 144

页数：4

相关论文

共 28 条

[1]

Boas L.V., 1987, COMPREHENSIVE COORDI

[2] IDENTIFICATION OF THE ZINC REDUCTION PRODUCT OF VCL3.3THF AS [V2CL3(THF)6]2[ZN2CL6] [J].

BOUMA, RJ ;

TEUBEN, JH ;

BEUKEMA, WR ;

BANSEMER, RL ;

HUFFMAN, JC ;

CAULTON, KG .

INORGANIC CHEMISTRY, 1984, 23 (17) :2715-2718

[3] PREPARATION AND STRUCTURES OF THE BINUCLEAR VANADIUM(II) COMPLEXES [L3V(MU-CL)3VL3]BPH4 (L = TETRAHYDROFURAN OR 3-METHYLTETRAHYDROFURAN) [J].

CANICH, JAM ;

COTTON, FA ;

DURAJ, SA ;

ROTH, WJ .

POLYHEDRON, 1987, 6 (06) :1433-1437

[4] VANADIUM(II)-FORMAMIDINATO AND VANADIUM(III)-FORMAMIDINATO COMPOUNDS - SYNTHESIS AND MOLECULAR-STRUCTURE OF V(FORM)2(NC5H5)2 AND V(ETA-5-C5H5)(FORM)2 [FORM=N,N'-DI-PARA-TOLYLFORMAMIDINE] [J].

COTTON, FA ;

POLI, R .

INORGANICA CHIMICA ACTA, 1988, 141 (01) :91-98

[5] SYNTHESIS AND CHARACTERIZATION OF 4 VANADIUM(II) COMPOUNDS, INCLUDING VANADIUM(II) SULFATE HEXAHYDRATE AND VANADIUM(II) SACCHARINATES [J].

COTTON, FA ;

FALVELLO, LR ;

LLUSAR, R ;

LIBBY, E ;

MURILLO, CA ;

SCHWOTZER, W .

INORGANIC CHEMISTRY, 1986, 25 (19) :3423-3428

[6] 4 COMPOUNDS CONTAINING OXO-CENTERED TRIVANADIUM CORES SURROUNDED BY 6 MU,ETA-2-CARBOXYLATO GROUPS [J].

COTTON, FA ;

EXTINE, MW ;

FALVELLO, LR ;

LEWIS, DB ;

LEWIS, GE ;

MURILLO, CA ;

SCHWOTZER, W ;

TOMAS, M ;

TROUP, JM .

INORGANIC CHEMISTRY, 1986, 25 (19) :3505-3512

[7] 2 COMPOUNDS CONTAINING THE TRIS(MU-CHLORO)HEXAKIS(TETRAHYDROFURAN)DIVANADIUM(II) CATION - PREPARATION, STRUCTURES, AND SPECTROSCOPIC CHARACTERIZATION [J].

COTTON, FA ;

DURAJ, SA ;

ROTH, WJ .

INORGANIC CHEMISTRY, 1985, 24 (06) :913-917

[8] STRUCTURAL STUDIES OF THE VANADIUM(II) AND VANADIUM(III) CHLORIDE TETRAHYDROFURAN SOLVATES [J].

COTTON, FA ;

DURAJ, SA ;

EXTINE, MW ;

LEWIS, GE ;

ROTH, WJ ;

SCHMULBACH, CD ;

SCHWOTZER, W .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1983, (23) :1377-1378

[9] ROLE OF THE LIGAND IN THE FORMATION OF SHORT VANADIUM VANADIUM CONTACTS - PREPARATION AND CRYSTAL-STRUCTURE OF MONOMERIC ([(PH2P)2CH]3V)[LI(THF)4](THF)2 AND [PHNC(H)NPH]2V(TMEDA) AND DIMERIC ([PHNC(ME)O]2V)2(TMEDA) (TMEDA=N,N,N',N'-TETRAMETHYLETHYLENEDIAMINE) [J].

EDEMA, JJH ;

MEETSMA, A ;

VANBOLHUIS, F ;

GAMBAROTTA, S .

INORGANIC CHEMISTRY, 1991, 30 (09) :2056-2061

[10]

EDEMA JJH, 1990, INORG CHEM, V29, P1303