(2,4-PENTANEDIONATO)VANADIUM(III) AND 2,4-PENTANEDIONATOVANADIUM(II) COMPLEXES - SYNTHESIS FROM THE OXOVANADIUM REDUCTIVE CHLORINATION AND THEIR STRUCTURAL CHARACTERIZATION

被引：11

作者：

SOLARI, E

DEANGELIS, S

FLORIANI, C

CHIESIVILLA, A

GUASTINI, C

机构：

[1] UNIV LAUSANNE,CHIM SECT,PL CHATEAU 3,CH-1005 LAUSANNE,SWITZERLAND

[2] UNIV PARMA,CNR,CTR STRUTT DIFFRATIOMETR,IST STRUTT CHIM,I-43100 PARMA,ITALY

来源：

INORGANIC CHEMISTRY | 1992年 / 31卷 / 01期

关键词：

D O I：

10.1021/ic00027a028

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

In spite of the recent active investigations on vanadium(III) and vanadium(II) chemistry, 2 there are still rather few starting materials easily accessible for (i) organometallic functionalization, (ii) reduction at the metal center, or (iii) solubility in organic solvents for carrying out reactions on oxygen-rich substrates, 3 except for the well-known VC13(THF)34 and [V2(μ-C13)(THF)6]+, 4 which, however, do not contain any ancillary ligands to be usable for the purposes outlined above. In this context we report the synthesis of some vanadium(III) and vanadium(II) acetylacetonate complexes. © 1992, American Chemical Society. All rights reserved.

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页码：141 / 144

页数：4

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