CONSECUTIVE CARBON-CARBON BOND FORMATION VIA THE PI-ALLYLPALLADIUM VARIANT OF THE HECK REACTION

被引：25

作者：

NYLUND, CS ^{[1
]}

KLOPP, JM ^{[1
]}

WEINREB, SM ^{[1
]}

机构：

[1] PENN STATE UNIV,DEPT CHEM,UNIV PK,PA 16802

来源：

TETRAHEDRON LETTERS | 1994年 / 35卷 / 25期

关键词：

D O I：

10.1016/S0040-4039(00)73335-1

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Two C-C bonds are readily formed by nucleophilic addition of stabilized carbanions to the pi-allylpalladium intermediate regioselectively produced by the Heck reaction of a vinyl bromide and an unactivated olefin. An intramolecular version of this condensation gives functionalized carbobicyclic compounds as products.

引用

页码：4287 / 4290

页数：4

共 27 条

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