PREPARATION OF (+)-TRICYCLO[6.2.1,0(2,7)]UNDEC-2(7)-EN-3-ONE AND ITS CONVERSION INTO (+)-EPI-BETA-SANTALENE

被引：7

作者：

KAMIKUBO, T ^{[1
]}

OGASAWARA, K ^{[1
]}

机构：

[1] TOHOKU UNIV, INST PHARMACEUT, SENDAI, MIYAGI 98077, JAPAN

来源：

CHEMISTRY LETTERS | 1995年 / 02期

关键词：

D O I：

10.1246/cl.1995.95

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Optically pure (+)-tricyclo[6.2.1.0(2,7)] undec-2(7)-en-3-one was first prepared from (+)-tricyclo[6.2.1.0(2,7)]undeca-4,9-dien-3-one in four steps. Conjugated addition occurred selectively from the methane-bridge side to give the 1,4-adduct which was converted into natural (+)-epi-beta-santalene.

引用

页码：95 / 96

页数：2

共 19 条

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