SYNTHESIS OF WATER-SOLUBLE LANTHANIDE PORPHYRIN SANDWICH COMPLEXES - BIS(TETRAPYRIDYLPORPHYRINATO) CERIUM(IV), [CE(TPYP)2], AND BIS(TETRAMETHYLPYRIDYLPORPHYRINATO) CERIUM(IV), [CE(TMPYP)2]

被引：18

作者：

JIANG, JZ ^{[1
]}

MACHIDA, K ^{[1
]}

ADACHI, G ^{[1
]}

机构：

[1] OSAKA UNIV, FAC ENGN, DEPT APPL CHEM, SUITA, OSAKA 565, JAPAN

来源：

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN | 1992年 / 65卷 / 07期

关键词：

D O I：

10.1246/bcsj.65.1990

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A reaction of tris(acetylacetonato) cerium(III), [Ce(acac)3], with tetrapyridylporphyrinato dilithium, Li2tpyp, produces a water-soluble sandwich complex bis(tetrapyridyl-porphyrinato) cerium(IV), [Ce(tpyp)2], in appreciable yield, which is followed by the same water-soluble sandwich complex bis(tetramethylpyridylporphyrinato) cerium(IV), [Ce(tmpyp)2], formed by methylation of the tpyp ligand in [Ce(tpyp)2].

引用

页码：1990 / 1992

页数：3

共 8 条

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