PHOTODECARBOXYLATION - MECHANISM AND SYNTHETIC UTILITY

被引：152

作者：

BUDAC, D ^{[1
]}

WAN, P ^{[1
]}

机构：

[1] UNIV VICTORIA, DEPT CHEM, BOX 3055, VICTORIA V8W 3P6, BC, CANADA

来源：

JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY | 1992年 / 67卷 / 02期

关键词：

D O I：

10.1016/1010-6030(92)85224-I

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The mechanistic aspects of photodecarboxylation are examined with respect to the mode of bond cleavage. Emphasis is placed on recent studies of aromatic substrates. The synthetic utility of photodecarboxylation is discussed with emphasis on reactions of carbon radicals generated via photodecarboxylation.

引用

页码：135 / 166

页数：32

共 124 条

[81] UBER DEN ABBAU VON INDOLDERIVATEN .1. PHOTOLYSE DURCH ULTRAVIOLETTES LICHT
MELCHIOR, GH
[J]. PLANTA, 1957, 50 (03) : 262 - 290
[82] PHOTOINDUCED DECARBOXYLATION OF ALIPHATIC ACIDS AND ESTERS IN SOLUTION - DEPENDENCE UPON STATE OF PROTONATION OF CARBOXYL GROUP
MITTAL, LJ
MITTAL, JP
HAYON, E
[J]. JOURNAL OF PHYSICAL CHEMISTRY, 1973, 77 (12) : 1482 - 1487
[83] A COMPARATIVE-STUDY OF THE PHOTOCHEMISTRY OF THE NON-STEROIDAL ANTI-INFLAMMATORY DRUGS, NAPROXEN, BENOXAPROFEN AND INDOMETHACIN
MOORE, DE
CHAPPUIS, PP
[J]. PHOTOCHEMISTRY AND PHOTOBIOLOGY, 1988, 47 (02) : 173 - 180
[84] STUDIES ON THE PHYTOALEXINS .31. SYNTHETIC STUDIES OF RISHITIN AND RELATED-COMPOUNDS .11. SYNTHESIS OF AUBERGENONE, A SESQUITERPENOID PHYTOALEXIN FROM DISEASED EGGPLANTS
MURAI, A
ABIKO, A
ONO, M
MASAMUNE, T
[J]. BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1982, 55 (04) : 1191 - 1194
[85] SELECTIVE PHOTOELECTROCHEMICAL OXIDATION OF VICINAL CYCLOHEXANEDICARBOXYLIC ACIDS - A MECHANISTIC STUDY
MUZYKA, JL
FOX, MA
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1990, 55 (01) : 209 - 215
[86] NAKAI H, 1982, SYNTHESIS-STUTTGART, P141
[87] PHOTOREDOX BEHAVIOR OF TRANSITION METAL-ETHYLENEDIAMINETETRAACETATE COMPLEXES - COMPARISON OF SOME GROUP VIII METALS
NATARAJAN, P
ENDICOTT, JF
[J]. JOURNAL OF PHYSICAL CHEMISTRY, 1973, 77 (17) : 2049 - 2054
[88] LASER FLASH AND STEADY-STATE PHOTOLYSIS OF BENOXAPROFEN IN AQUEOUS-SOLUTION
NAVARATNAM, S
HUGHES, JL
PARSONS, BJ
PHILLIPS, GO
[J]. PHOTOCHEMISTRY AND PHOTOBIOLOGY, 1985, 41 (04) : 375 - 380
[89] CHEMICALLY-INDUCED NUCLEAR-POLARIZATION - COMPARATIVE-STUDY OF THERMAL AND PHOTOCHEMICAL DECOMPOSITION OF ACYL BENZOYL PEROXIDES
NEDELEC, JY
LEFORT, D
[J]. TETRAHEDRON, 1980, 36 (22) : 3199 - 3203
[90] MECHANISM OF FLAVIN 4A SUBSTITUTION WHICH ACCOMPANIES PHOTOLYTIC DECARBOXYLATION OF ALPHA-SUBSTITUTED ACETIC-ACIDS - CARBANION VS RADICAL INTERMEDIATES
NOVAK, M
MILLER, A
BRUICE, TC
TOLLIN, G
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1980, 102 (04) : 1465 - 1467

← 4 5 6 7 8 9 10 11 12 13 →