HIGH-RESOLUTION FOURIER SPECTROMETRY OF N-14(2) VIOLET EMISSION-SPECTRUM - EXTENSIVE ANALYSIS OF THE C-3-PI(U)-]B-3-PI(G) SYSTEM

被引：75

作者：

ROUX, F ^{[1
]}

MICHAUD, F ^{[1
]}

VERVLOET, M ^{[1
]}

机构：

[1] UNIV PARIS 11,PHOTOPHYS MOLEC LAB,F-91405 ORSAY,FRANCE

来源：

JOURNAL OF MOLECULAR SPECTROSCOPY | 1993年 / 158卷 / 02期

关键词：

D O I：

10.1006/jmsp.1993.1071

中图分类号：

O64 [物理化学（理论化学）、化学物理学]; O56 [分子物理学、原子物理学];

学科分类号：

070203 ; 070304 ; 081704 ; 1406 ;

摘要：

Rotational analysis of the C3Πu → B3Πg system of 14N2 has been extended to include the vibrational levels of the C3Πu state (v = 1 → 4). The v = 5 level is not observed. Equilibrium constants of this state are deduced. RKR potential energy curves for the two states are constructed, and the Franck-Condon factors are calculated for the C3Πu → B3Πg transition. Except for one in the v = 1 level, weak rotational perturbations are localized to a few rotational levels. © 1993 Academic Press, Inc.

引用

页码：270 / 277

页数：8

共 18 条

[1]

ANTONOV EE, 1989, OPT SPECTROSC USSR G, V7, P172

[2] LAMBDA-TYPE DOUBLING PARAMETERS FOR MOLECULES IN PI-ELECTRONIC STATES OF TRIPLET AND HIGHER MULTIPLICITY [J].