MODIFICATION OF Pt SURFACES, The mechanism of the improvement of reforming catalysts

被引:13
作者
Ponec, V. [1 ]
机构
[1] Leiden Univ, Gorlaeus Labs, NL-2300 RA Leiden, Netherlands
关键词
D O I
10.1016/0920-5861(91)80004-S
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
Reactions of n-hexane on three bimetallic (alloy) systems: Pt-Re. Pt-Ir, Pt-Co have been studied with sulphur-free and sulphided catalysts. A shift is observed in the selectivity pattern from "metallic: (on sulphur free catalysts) to "acid catalysed" reactions (on sulphur modified catalysts), which is explained by the shift in the formation of certain intermediates of the reaction.
引用
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页码:251 / 258
页数:8
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