ORGANOMETALLIC CHEMISTRY OF DIPHOSPHAZANES .4. REACTIONS OF THE CYCLODIPHOSPHAZANE, CIS-[TERT-BUNP(OPH)]2 WITH M(CO)6 (M = CR, MO, W), RHODIUM(I), PALLADIUM(II) AND PLATINUM(II) DERIVATIVES

被引：19

作者：

BALAKRISHNA, MS ^{[1
]}

KRISHNAMURTHY, SS ^{[1
]}

机构：

[1] INDIAN INST SCI,DEPT INORGAN & PHYS CHEM,BANGALORE 560012,KARNATAKA,INDIA

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1992年 / 424卷 / 02期

关键词：

D O I：

10.1016/0022-328X(92)83153-9

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reactions of the cyclodiphosphazane, cis-[(t)BuNP(OPh)]2(L) with M(CO)6 (M = Cr, Mo or W) as well as Pd(II) and Pt(II) derivatives afford mononuclear complexes of the type [M(CO)4L2] (M = Cr, Mo or W) and [MCl2L2] (M = Pt or Pd) in which the cyclodiphosphazane acts as a monodentate ligand. Reactions with Rh(I) derivatives yield the complexes [Rh(COD)LCl] (COD = 1,5-cyclooctadiene) and [RhCl(CO)(mu-L)]2 in which the cyclodiphosphazane exhibits monodentate and bridged-bidentate modes of coordination, respectively. The structures of the complexes have been deduced mainly from P-31 NMR spectroscopic data.

引用

页码：243 / 251

页数：9

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