LUMINESCENCE OF EU(III) IN (NH4)3YCL6 - NONRADIATIVE-TRANSITIONS INDUCED BY THE 2ND COORDINATION SPHERE

被引：12

作者：

BLASSE, G

DIRKSEN, GJ

机构：

[1] Debye Research Institute, University of Utrecht, 3508 TA Utrecht, P.O. Box 80

来源：

JOURNAL OF SOLID STATE CHEMISTRY | 1992年 / 96卷 / 01期

关键词：

D O I：

10.1016/S0022-4596(05)80319-6

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The quantum efficiency of the luminescence of Eu(III) in (NH4)3YCl6 is considerably suppressed due to the presence of high-frequency oscillators (NH+4) in the second coordination sphere of the europium ion. Additional evidence for this effect is found in the vibronic emission lines of Gd(III) in (NH4)2GdCl5. © 1992 Academic Press, Inc.

引用

页码：258 / 262

页数：5

共 23 条

[1]

BLASSE G, 1988, RECL TRAV CHIM PAY B, V107, P138

[2] VIBRONIC LINES IN THE GD3+ EMISSION-SPECTRUM DUE TO COUPLING WITH THE 2ND COORDINATION SPHERE - GD(CLO4)3.6H2O [J].