A NOVEL SYNTHESIS OF H3PF2 BY SELECTIVE FLUORINATION OF H3P - THE IR-SPECTRA AND NORMAL-COORDINATE ANALYSES OF THE SERIES HND3-NPF2

被引：7

作者：

BECKERS, H

机构：

[1] Bergische Universität-, Gesamthochschule Fachbereich, Wuppertal

来源：

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 1993年 / 619卷 / 11期

关键词：

DIFLUOROPHOSPHORANE; PREPARATION; IR SPECTRA; NORMAL COORDINATE ANALYSIS;

D O I：

10.1002/zaac.19936191110

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The synthesis by selective low temperature fluorination of H3P with XeF2 in CF2HCI at - 78-degrees-C of H3PF2, which was hitherto not available as pure material on a preparative scale, affords crystalline material whose thermal stability is higher than expected. Gas phase IR spectra of H3PF2 and its deuterated isotopomers HnD3-nPF2 (n = 0-3) have been measured and assigned, and force constants have been calculated by means of a normal coordinate analysis based on 35 experimental wavenumbers.

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页码：1869 / 1879

页数：11

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