ALKALI-METAL FLUORIDE MEDIATED SILYL-REFORMATSKY REACTION IN SOLID-LIQUID MEDIA - ACTIVATION BY MICROWAVES

被引：52

作者：

LATOUCHE, R ^{[1
]}

TEXIERBOULLET, F ^{[1
]}

HAMELIN, J ^{[1
]}

机构：

[1] UNIV RENNES 1,PHYSICOCHIM STRUCT GRP 3,CNRS,CAMPUS BEAULIEU,F-35042 RENNES,FRANCE

来源：

TETRAHEDRON LETTERS | 1991年 / 32卷 / 09期

关键词：

D O I：

10.1016/S0040-4039(00)92038-0

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Condensation of trimethylsilylacetonitrile or ethyltrimethylsilylacetate with benzaldehyde, in the presence of dried alcali metal fluorides in heterogeneous media under microwaves leads readily to beta-trimethylsilyloxynitrile or ester according to a Reformatsky type reaction. The later products could be hydrolyzed and dehydrated on the wet inorganic salt to give the corresponding alkenes.

引用

页码：1179 / 1182

页数：4

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