FLUORESCENCE PROPERTIES OF CU+ ION IN PHOSPHATE-GLASSES OF THE BALIPO4-P2O5 SYSTEM

被引:26
作者
BOUTINAUD, P [1 ]
DULOISY, E [1 ]
PEDRINI, C [1 ]
MOINE, B [1 ]
PARENT, C [1 ]
LEFLEM, G [1 ]
机构
[1] UNIV LYON 1, CNRS, URA 442, F-69622 VILLEURBANNE, FRANCE
关键词
D O I
10.1016/0022-4596(91)90188-N
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The spectroscopy and the excited state dynamics of Cu+ ion in phosphate glasses are investigated as a function of the copper concentration and temperature. The blue fluorescence is assigned to single Cu+ impurity ions occupying various sites. An additional red fluorescence, not detected in weakly Cu-doped samples but which grows with copper concentration, is well interpreted in terms of (Cu+)2 pair centers. © 1991.
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收藏
页码:236 / 243
页数:8
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