LOCALIZATION OF ELECTRONIC EXCITATION-ENERGY IN RU(2,2'-BIPYRIDINE)2(2,2'-BIPYRIDINE-4,4'-DICARBOXYLIC ACID)2+ AND RELATED COMPLEXES

被引：67

作者：

FERGUSON, J ^{[1
]}

MAU, AWH ^{[1
]}

SASSE, WHF ^{[1
]}

机构：

[1] CSIRO,DIV APPL ORGAN CHEM,MELBOURNE 3001,VICTORIA,AUSTRALIA

来源：

CHEMICAL PHYSICS LETTERS | 1979年 / 68卷 / 01期

关键词：

D O I：

10.1016/0009-2614(79)80058-5

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The absorption spectra of Ru(2,2′-bipyridine)2 (2,2′-bipyridine-4,4′-dicarboxylic acid)2+ (I) and its diethyl ester (II) are closely related and are both significantly different from the spectra of the mono-protonated (Ia) and deprotonated (Ib) complexes. Luminescence polarization measurements show that for I and II the luminescent states have the transferred electron in the bipy-4,4′(COOH)2 and bipy-4,4′(COOEt)2 ligands, respectively, rather than in the unsubstituted bipy ligands. © 1979.

引用

页码：21 / 24

页数：4

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