LOW POTENTIAL ANODIC POLYMERIZATION OF BENZENE IN METHANESULFONIC AND TRIFLUOROMETHANESULFONIC ACID-SOLUTIONS

被引：5

作者：

GOLDENBERG, LM ^{[1
]}

AEIYACH, S ^{[1
]}

LACAZE, PC ^{[1
]}

机构：

[1] UNIV PARIS 07,ITODYS,CNRS,URA 34,1 RUE GUY DE LA BROSSE,F-75221 PARIS 05,FRANCE

来源：

SYNTHETIC METALS | 1992年 / 51卷 / 1-3期

关键词：

D O I：

10.1016/0379-6779(92)90290-Y

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

By using three-component mixtures: benzene, strong acid, and trifluoroacetic acid it is possible to electropolymerize benzene in a single-phase medium of strong acidity at about 1.3 V for methanesulfonic acid and 1 V for triflic acid (CF3SO3H). In the latter case, voltammograms with sharp peaks could be observed; these gradually convert to the usual ones with broad redox peaks. Such a poly(p-phenylene) behaviour in superacid media can be attributed to the formation of linear chains with a narrow distribution of the degree of polymerization.

引用

页码：349 / 353

页数：5

共 9 条

[1] A NEW METHOD FOR OBTAINING POLYPARAPHENYLENE FILMS BY ELECTROCHEMICAL OXIDATION OF (BENZENE-SBF5) PI-COMPLEXES IN SO2 MEDIUM [J].

AEIYACH, S ;

SOUBIRAN, P ;

LACAZE, PC ;

FROYER, G ;

PELOUS, Y .

SYNTHETIC METALS, 1989, 32 (01) :103-112

[2] ELECTROPOLYMERIZATION OF BENZENE AND BIPHENYL IN ORGANIC MEDIA - INFLUENCE OF DIFFERENT PARAMETERS (SOLVENT, WATER, ACIDITY, SALT) ON THE FORMATION OF POLYPARAPHENYLENE FILMS (PPP) [J].

AEIYACH, S ;

LACAZE, PC .

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 1989, 27 (02) :515-526

[3] INVESTIGATION OF POLY-(PARA-PHENYLENE) OBTAINED IN ELECTROCHEMICAL OXIDATION OF BENZENE IN THE BUPYCL-ALCL3 MELT AND IN ORGANIC-SOLVENTS WITH OLEUM [J].

GOLDENBERG, LM ;

PELEKH, AE ;

KRINICHNYI, VI ;

ROSHCHUPKINA, OS ;

ZUEVA, AF ;

LYUBOVSKAYA, RN ;

EFIMOV, ON .

SYNTHETIC METALS, 1991, 43 (1-2) :3071-3074

[4] INVESTIGATION OF POLY(P-PHENYLENE) OBTAINED BY ELECTROCHEMICAL OXIDATION OF BENZENE IN A BUPYCL-ALCL3 MELT [J].

GOLDENBERG, LM ;

PELEKH, AE ;

KRINICHNYI, VI ;

ROSHCHUPKINA, OS ;

ZUEVA, AF ;

LYUBOVSKAYA, RN ;

EFIMOV, ON .

SYNTHETIC METALS, 1990, 36 (02) :217-228

[5] ELECTROPOLYMERIZATION OF BENZENE IN A 2-PHASE BENZENE ACID SYSTEM - COMPARATIVE-STUDY IN STRONG PROTON ACID AND SUPERACID MEDIA [J].

GOLDENBERG, LM ;

AEIYACH, S ;

LACAZE, PC .

JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1992, 327 (1-2) :173-184

[6] OLEUM AS AN ELECTROLYTE OF ANODIC POLYMERIZATION OF BENZENE [J].

GOLDENBERG, LM ;

ROSCHUPKINA, OS ;

TITKOV, AN .

SYNTHETIC METALS, 1991, 44 (01) :107-110

[7] ELECTROCHEMICAL SOLID-STATE STUDIES ON OLIGOMERIC PARA-PHENYLENES AS MODEL COMPOUNDS FOR CONDUCTIVE POLYMERS [J].

MEERHOLZ, K ;

HEINZE, J .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1990, 29 (06) :692-695

[8] SOLID-STATE ELECTROCHEMICAL EXPERIMENTS ON DEFINED OLIGOMERS OF THE POLY-PARA-PHENYLENE-SERIES AS MODELS OF CONDUCTING POLYMERS [J].

MEERHOLZ, K ;

HEINZE, J .

SYNTHETIC METALS, 1991, 43 (1-2) :2871-2876

[9] ELECTROSYNTHESIS AND SPECTROSCOPIC CHARACTERIZATION OF POLY-PARA-PHENYLENE FILMS PREPARED BY OXIDATION OF BENZENE IN LIQUID SULFUR-DIOXIDE [J].

SOUBIRAN, P ;

AEIYACH, S ;

AARON, JJ ;

DELAMAR, M ;

LACAZE, PC .

JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1988, 251 (01) :89-102

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