TA(110) SURFACE AND SUBSURFACE CORE-LEVEL SHIFTS AND 4F7/2 LINE-SHAPES

High-resolution 4f core-level spectra of the Ta(110) surface region have been obtained at 80 and 300 K with 70- and 100-eV synchrotron radiation. The data show that the subsurface core-level binding-energy shift (compared to deeper-lying atoms) for a close-packed bcc(110) surface can be substantial: 65+/-15 meV for the first underlayer atoms of Ta(110). The surface core-level shift is 360+/-12 meV at 80 K and decreases by 13+/-2 meV at 300 K. Final-state screening in both the bulk and surface layers is well described by a constant singularity index of 0.133+/-0.012. An enhanced phonon broadening at the surface corresponds to a reduced perpendicular Debye temperature for the surface atoms of 128+/-18 K compared to the bulk Debye temperature of 225 K.