FRAGMENTATION OF, AND OXYGEN-ATOM ABSTRACTION BY, (CP-ASTERISK-RE(O))(2)(MU-O)(2)

被引:28
作者
GABLE, KP
JULIETTE, JJJ
GARTMAN, MA
机构
[1] Department of Chemistry, Oregon State University, Corvallis
关键词
D O I
10.1021/om00007a007
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The dimeric oxo complex (Cp*ReO)(2)(mu-O)(2) is found to be in equilibrium with a monomeric form, proposed to be Cp*ReO2. The mixture of monomer and dimer stereospecifically abstracts oxygen from epoxides to make alkene plus Cp*ReO3.
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页码:3138 / 3140
页数:3
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