A NEW LIGAND ENVIRONMENT IN ORGANOLANTHANOID CHEMISTRY - STERICALLY HINDERED, CHELATING DIOLATO LIGANDS AND THE X-RAY STRUCTURE OF [LA((CH(SIME3)2)(1,1'-(2-OC6H2BUT2-3,5)2)(THF)3] (THF = TETRAHYDROFURAN)

被引：82

作者：

SCHAVERIEN, CJ ^{[1
]}

MEIJBOOM, N ^{[1
]}

ORPEN, AG ^{[1
]}

机构：

[1] UNIV BRISTOL,SCH CHEM,BRISTOL BS8 1TS,AVON,ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1992年 / 02期

关键词：

D O I：

10.1039/c39920000124

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

[La{CH(SiMe3)2}3] 1 reacts with 1 equiv. of 3,3',5,5'-tetra-tert-butylbiphenyl-2,2'-diol 2 to afford the monomeric chelate [La{CH(SiMe3)2}{1,1'-(2-OC6H2Bu(t)2-3,5)2}] 4, whose mono-5, and crystallographically characterised tris-thf adducts 6 have been synthesized; its reaction with 3,3'-bis(triphenylsilyl)-1,1'-binaphthyl-2,2'-diol 3c affords [La{CH(SiMe3)2}{1,1'-(2-OC10H5SiPh3-3)2}(OEt2)] 7.

引用

页码：124 / 126

页数：3

共 25 条

[11] MARKS TJ, 1978, J AM CHEM SOC, V100, P7112
[12] MARKS TJ, 1979, ORGANOMETALLICS F EL, P137
[13] UNPRECEDENTED STEREOCHEMICAL CONTROL IN THE CLAISEN REARRANGEMENT OF ALLYL VINYL ETHERS USING ORGANO-ALUMINUM REAGENTS
MARUOKA, K
NONOSHITA, K
BANNO, H
YAMAMOTO, H
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1988, 110 (23) : 7922 - 7924
[14] METHYLALUMINUM BIS(2,6-DI-TERT-BUTYL-4-METHYLPHENOXIDE) AS A PROTECTING GROUP FOR MULTIFUNCTIONAL MOLECULES - SYNTHETIC UTILITY IN SELECTIVE CARBONYL REDUCTIONS
MARUOKA, K
ARAKI, Y
YAMAMOTO, H
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1988, 110 (08) : 2650 - 2652
[15] EFFICIENT SYNTHESIS OF STERICALLY HINDERED CHIRAL BINAPHTHOL DERIVATIVES
MARUOKA, K
ITOH, T
ARAKI, Y
SHIRASAKA, T
YAMAMOTO, H
[J]. BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1988, 61 (08) : 2975 - 2976
[16] ASYMMETRIC ENE REACTION CATALYZED BY CHIRAL ORGANO-ALUMINUM REAGENT
MARUOKA, K
HOSHINO, Y
SHIRASAKA, T
YAMAMOTO, H
[J]. TETRAHEDRON LETTERS, 1988, 29 (32) : 3967 - 3970
[17] ASYMMETRIC HETERO-DIELS-ALDER REACTION CATALYZED BY CHIRAL ORGANO-ALUMINUM REAGENT
MARUOKA, K
ITOH, T
SHIRASAKA, T
YAMAMOTO, H
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1988, 110 (01) : 310 - 312
[18] MIYATAKE T, 1989, MAKROMOL CHEM-RAPID, V10, P349
[19] THE ASYMMETRIC DIELS-ALDER REACTION BY THE USE OF A CATALYTIC AMOUNT OF A CHIRAL TITANIUM REAGENT
NARASAKA, K
INOUE, M
YAMADA, T
[J]. CHEMISTRY LETTERS, 1986, (11) : 1967 - 1968
[20] ASYMMETRIC-SYNTHESIS VIA AXIALLY DISSYMMETRIC MOLECULES - A BINAPHTHOL-MODIFIED COMPLEX ALUMINUM-HYDRIDE REAGENT POSSESSING EXTREMELY HIGH ABILITY OF CHIRAL RECOGNITION
NOYORI, R
[J]. PURE AND APPLIED CHEMISTRY, 1981, 53 (12) : 2315 - 2322

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