SYNTHESIS OF METAL FULLERENE DERIVATIVES FROM CHLORO HYDRIDO TRANSITION-METAL COMPLEXES

被引：22

作者：

SCHREINER, S ^{[1
]}

GALLAHER, TN ^{[1
]}

PARSONS, HK ^{[1
]}

机构：

[1] JAMES MADISON UNIV,HARRISONBURG,VA 22807

来源：

INORGANIC CHEMISTRY | 1994年 / 33卷 / 13期

关键词：

D O I：

10.1021/ic00091a051

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reaction of the chloro hydrido transition metal complexes [Pt(H)(Cl)(PPh3)2] and [Ir(H)2(CO)-(Cl)(PPh3)2] with C60 in refluxing ethanol/benzene in the presence of ethanolic NaOH results in the formation of [Pt(eta2-C60)(PPh3)2] and [Ir(H)(CO)-(eta2-C60)(PPh3)2], respectively. The proposed structure of the novel, green [Ir(H)(CO)(eta2-C60)(FPh3)2] complex is based on elemental analysis, IR and multinuclear NMR spectroscopy.

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页码：3021 / 3022

页数：2

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