SYNTHESIS, CRYSTAL, AND MOLECULAR-STRUCTURE OF THE PALLADIUM(0)-FULLERENE DERIVATIVE (ETA-2-C60)PD(PPH3)2

被引:133
作者
BASHILOV, VV
PETROVSKII, PV
SOKOLOV, VI
LINDEMAN, SV
GUZEY, IA
STRUCHKOV, YT
机构
[1] Institute of Organo-Element Compounds, Academy of Sciences of Russia, Moscow 117813
关键词
D O I
10.1021/om00028a003
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Buckminsterfullerene, C60, reacts with Pd-(PPh3)4 in solution to give in high yield a palladium(0) complex, (C60)Pd(PPh3)z in which fullerene is ligated in a eta2 fashion. The molecular structure of this compound has been established by the X-ray study of a single crystal.
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收藏
页码:991 / 992
页数:2
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