NONPHOTOCHEMICAL SYNTHESIS AND STRUCTURE OF THE 1ST DONOR-STABILIZED [BIS(SILYLENE)]RUTHENIUM COMPLEX

被引：54

作者：

TOBITA, H

WADA, H

UENO, K

OGINO, H

机构：

[1] Department of Chemistry, Faculty of Science, Tohoku University, Aoba-ku

来源：

ORGANOMETALLICS | 1994年 / 13卷 / 07期

关键词：

D O I：

10.1021/om00019a003

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The first donor-stabilized [bis(silylene)]ruthenium compex, Cp(Ph3P)Ru(SiMe2---O(Me)---SiMe2), has been synthesized by the thermal reaction of CpRu(Pph3)2Me with HMe2SiSiMe2OMe. The X-ray crystal structure analysis of this complex revealed its distorted-piano-stool structure, containing a RuSi2O four-membered chelate ring with two short Ru-Si bonds and two long Si-O bonds.

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页码：2545 / 2547

页数：3

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