ON DEUTERIUM-LABELING STUDIES FOR PROBING RHODIUM-CATALYZED HYDROBORATION REACTIONS

被引：34

作者：

BURGESS, K

VANDERDONK, WA

KOOK, AM

机构：

[1] Rice University, Department of Chemistry, Houston, Texas 77251

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1991年 / 56卷 / 09期

关键词：

D O I：

10.1021/jo00009a002

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Reactions of deuteriocatecholborane (C6H4O2BD) with alkenes in the presence of rhodium(+1) complexes have been reinvestigated. Distributions of label in the products differ significantly from those reported previously, and alternative rationales for these observations are provided.

引用

页码：2949 / 2951

页数：3

共 12 条

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