Synthesis and Photocatalytic Activity of TiO2-ZrO2 Nano-Sized Powders by Sol-Gel Process

被引:4
作者
Han, Jae-Kil [1 ]
Saito, Fumio [2 ]
Park, Jong-Gu [3 ]
Lee, Byong-Taek [1 ]
机构
[1] Kongju Natl Univ, Sch Adv Mat Engn, Chungnam 314701, South Korea
[2] Tohoku Univ, Inst Multidisciplinary Res Adv Mat, Sendai, Miyagi 9808577, Japan
[3] Korea Inst Sci & Technol, Nano Mat Technol Ctr, Seoul 136791, South Korea
关键词
Nanocrystalline; TiO2ZrO2 nano-sized powders; Methyl orange; Photocatalytic activity; Sol-gel method;
D O I
10.4191/kcers.2005.42.1.007
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
TiO2-ZrO2 powders were successfully synthesized by the sol-gel process using titanium iso-propoxide as a precursor. The amorphous TiO2 particles, 70 nm in size, homogenously adhered to the surface of ZrO2 the powders. After calcination at 450 degrees C, most of the TiO2 powders appeared as an anatase type, whereas they changed to a rutile phase at 750 degrees C. For comparison of photocatalytic activity, TiO2-ZrO2 nano-sized powders calcined at 450 degrees C, 600 degrees C, and 750 degrees C were used. In the TiO2-20 wt%ZrO2 powders calcined at 450 degrees C, there was excellent removal efficiency of Methyl Orange (MO). For the calcination temperature increased, TiO2ZrO2 nano-sized powders increased ZrO2 contents showed the good photoactivity for the photooxidation of MO.
引用
收藏
页码:7 / 10
页数:4
相关论文
共 19 条
[1]   Photocatalytic TiO2 deposition by chemical vapor deposition [J].
Byun, D ;
Jin, Y ;
Kim, B ;
Lee, JK ;
Park, D .
JOURNAL OF HAZARDOUS MATERIALS, 2000, 73 (02) :199-206
[2]   Photocatalyzed oxidation of alcohols and organochlorides in the presence of native TiO2 and metallized TiO2 suspensions.: Part (I):: Photocatalytic activity and pH influence [J].
Chen, J ;
Ollis, DF ;
Rulkens, WH ;
Bruning, H .
WATER RESEARCH, 1999, 33 (03) :661-668
[3]   Preparation, physico-chemical characterization and catalytic activity of sulphated ZrO2-TiO2 mixed oxides [J].
Das, D ;
Mishra, HK ;
Parida, KM ;
Dalai, AK .
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2002, 189 (02) :271-282
[4]   Photocatalysis for oxidation of phenol and reduction of inorganic pollutants by nanocrystalline TiO2-ZrO2 powders [J].
Han, JK ;
Choi, SM ;
Oh, IH ;
Saito, F ;
Lee, BT .
DESIGNING, PROCESSING AND PROPERTIES OF ADVANCED ENGINEERING MATERIALS, PTS 1 AND 2, 2004, 449-4 :289-292
[5]   Microstructures of porous Al2O3-50 wt.% ZrO2 composites using in-situ synthesized Al2O3-ZrO2 composite powders [J].
Han, JK ;
Saito, F ;
Lee, BT .
MATERIALS LETTERS, 2004, 58 (16) :2181-2185
[6]   Photoactivity and phase stability of ZrO2-doped anatase-type TiO2 directly formed as nanometer-sized particles by hydrothermal conditions [J].
Hirano, M ;
Nakahara, C ;
Ota, K ;
Tanaike, O ;
Inagaki, M .
JOURNAL OF SOLID STATE CHEMISTRY, 2003, 170 (01) :39-47
[7]   Preparation of stable anatase-type TiO2 and its photocatalytic performance [J].
Inagaki, M ;
Nakazawa, Y ;
Hirano, M ;
Kobayashi, Y ;
Toyoda, M .
INTERNATIONAL JOURNAL OF INORGANIC MATERIALS, 2001, 3 (07) :809-811
[8]   Quantum yields of active oxidative species formed on TiO2 photocatalyst [J].
Ishibashi, K ;
Fujishima, A ;
Watanabe, T ;
Hashimoto, K .
JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY, 2000, 134 (1-2) :139-142
[9]   Characterization of Al2O3-ZrO2 mixed oxide catalytic supports prepared by the sol-gel method [J].
Klimova, T ;
Rojas, ML ;
Castillo, P ;
Cuevas, R ;
Ramirez, J .
MICROPOROUS AND MESOPOROUS MATERIALS, 1998, 20 (4-6) :293-306
[10]   Preparation and characterization of nano-TiO2 powder [J].
Li, BR ;
Wang, XH ;
Yan, MY ;
Li, LT .
MATERIALS CHEMISTRY AND PHYSICS, 2003, 78 (01) :184-188