FLUOROPLATINATES(IV) OF THE LANTHANIDES LNF[PTF6] (LN = PR, SM, GD, TB, DY, HO, ER)

被引：8

作者：

SCHROTTER, F ^{[1
]}

MULLER, BG ^{[1
]}

机构：

[1] JUSTUS LIEBIG UNIV,INST ANORGAN & ANALYT CHEM I,HEINRICH BUFF RING 58,D-35392 GIESSEN,GERMANY

来源：

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 1993年 / 619卷 / 08期

关键词：

FLUOROPLATINATES(IV); PREPARATION; SINGLE CRYSTAL STRUCTURE;

D O I：

10.1002/zaac.19936190819

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

For the first time fluorides LnF[PtF6] (Ln = Pr, Sm, Gd, Th, Dy, Ho, Er), all yellow have been obtained. From single crystal data they crystallize monoclinic, space group P2(1)/n-C2h5 (No. 14), Z = 4, Pr: a = 1125.77(19) pm, b = 559.04(7) pm, c = 910.27(17) pm, beta 107.29(1)-degrees; Sm: a = 1114.63(31) pm, b = 552.70(12) pm, c = 898.02(20) pm, beta = 107.24(2)-degrees; Gd: a = 1112.12(15) pm, b = 551.22(7) pm, c = 891.99(11) pm, beta = 107.09(1)-degrees; Th (Powder data): a = 1108.88(20) pm, b = 552.71(9) pm, c = 889.56(16) pm, beta = 107.30(1)-degrees; Dy: a = 1100.28(23) pm, b = 547.77(8) pm, c = 882.41(13) pm, beta = 107.32(1); Ho: a = 1099.11(16) pm, b = 546.16(7) pm, c = 879.45(15) pm, beta = 107.34(1)-degrees; Er: a = 1095.10(16) pm, b = 544.82(10) pm, c = 874.85(14) pm, 8 = 107.37(1)-degrees.

引用

页码：1431 / 1440

页数：10

共 11 条

[1]

BENNER G, 1991, THESIS U GIESSEN

[2] RARE-EARTH FLUORONIOBATES, LNNBF7 [J].

BIZOT, D ;

CHASSAING, J ;

ERB, A .

JOURNAL OF THE LESS-COMMON METALS, 1981, 79 (01) :39-45

[3] CRYSTAL-CHEMISTRY OF THE FLUORIDE MOF4 AND THE FLUOROMOLYBDATES LNMOF7 (LN = LANTHANIDE) [J].

COUTURIER, JC ;

ANGENAULT, J ;

MARY, Y ;

QUARTON, M .

JOURNAL OF THE LESS-COMMON METALS, 1988, 138 (01) :71-77

[4] EFFECTIVE COORDINATION NUMBERS (ECON) AND MEAN FICTIVE IONIC-RADII (MEFIR) [J].

HOPPE, R .

ZEITSCHRIFT FUR KRISTALLOGRAPHIE, 1979, 150 (1-4) :23-52

[5] ON COMPLEX FLUORIDES WITH CU-2+ AND PD-2+ - PDPTF6, CUPTF6 AND RBCUPDF5 [J].

MULLER, BG .

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1988, 556 (01) :79-84

[6] RARE-EARTH FLUOROZIRCONATES LNZRF7 [J].

POULAIN, M ;

LUCAS, J .

MATERIALS RESEARCH BULLETIN, 1972, 7 (04) :319-&

[7] CRYSTAL-STRUCTURE OF SMZRF7 - STRUCTURAL RELATIONS TO REO3-TYPE [J].

POULAIN, M ;

LUCAS, J .

JOURNAL OF SOLID STATE CHEMISTRY, 1973, 8 (02) :132-141

[8] THE STRUCTURE OF CUBIC YBZRF7 [J].

POULAIN, M ;

TOFIELD, BC .

JOURNAL OF SOLID STATE CHEMISTRY, 1981, 39 (03) :314-328

[9] CRYSTAL-STRUCTURE OF TERNARY CU(II) FLUORIDES CUM(IV)F6 (M(IV) = SN,PB,TI,MN,PD) [J].

SCHROTTER, F ;

MULLER, BG .

ZEITSCHRIFT FUR KRISTALLOGRAPHIE, 1991, 196 (1-4) :261-268

[10]

SHELDRICK G, 1976, SHELX PROGRAMMSYSTEM

← 1 2 →