OPTICAL PHONONS AND SYMMETRY OF TYSONITE LANTHANIDE FLUORIDES

被引:39
作者
LOWNDES, RP
PARRISH, JF
PERRY, CH
机构
[1] Spectroscopy Laboratory and Research Laboratory of Electronics, Massachusetts Institute of Technology, Cambridge
[2] Department of Physics, Northeastern University, Boston
来源
PHYSICAL REVIEW | 1969年 / 182卷 / 03期
基金
美国国家科学基金会; 美国国家航空航天局;
关键词
D O I
10.1103/PhysRev.182.913
中图分类号
O4 [物理学];
学科分类号
0702 ;
摘要
The polarized infrared reflectance of LaF3, CeF3, PrF3, and NdF3 has been measured from 40 to 500 cm-1 at 295, 78, and 7°K. Kramers-Kronig analyses of the reflectance spectra yield evidence for eleven infraredactive phonons in the polarization (Ec) and six in the polarization (Ec). These results, together with reported magnetic-resonance measurements, are consistent with a P3c1 magnetic space group. A theory and method for directly observing the longitudinal optical phonon frequencies of strongly anisotropic crystals in transmission are reported. © 1969 The American Physical Society.
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页码:913 / &
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